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Yes, the same Bucky Barnes who became the Winter Soldier.
During the course of the Civil War comic book storyline (which we will all see unfold next year in Captain America: Civil War), it is revealed that Natasha and Bucky actually had a relationship when both were training to be operatives.
When Bucky later becomes Captain America (long story that I just don't have the heart to reveal guys), he and Natasha date again for quite a while before things end once more. She and Tony even get engaged, but she is later revealed to be a traitor to the Avengers and is killed by Hawkeye.
There are also two alternate universes where Natasha dates both Count Otto Von Doom, aka the bad guy from The Fantastic Four series, as well as Tony Stark. Thankfully, it doesn't seem like the Marvel filmmakers will be adding that storyline in — at least I hope not.
Their working relationship became so strong that Matt even broke up with Karen Page to be with Natasha.
Many people date more than one person in their lifetime.The actors were asked what they thought about fans 'shipping the Black Widow — aka Natasha — with many of the other Avengers.In response, the actors jokingly called her a "slut" and a "whore." While the jokes and name-calling are pretty stupid and have (rightfully) outraged many fans, there is one point that needs to be brought up about this whole mess: Black Widow's love life. In the comics, Black Widow has in fact had her fair share of romances from Hercules to Daredevil.Many people get married more than once in their lifetime.There doesn't have to be any negative connotation to this. Natasha was once married to a man named Alexei Shostakov while she was still an operative in Russia.
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got dressed up as the pink Power Ranger to get an up close look at the convention without being noticed by fans.